Importance of the Lu-Hf isotopic system in studies of planetary chronology and chemical evolution     

P.Jonathan Patchett 《Geochimica et cosmochimica acta》1983,47(1):81-91

The ¹⁷⁶Lu-¹⁷⁶Hf isotope method and its applications in earth sciences are discussed. Greater fractionation of Lu/Hf than Sm/Nd in planetary magmatic processes makes ${}^{176}\text{Hf}{}^{177}\text{Hf}$ a powerful geochemical tracer. In general, proportional variations of ${}^{176}\text{Hf}{}^{177}\text{Hf}$ exceed those of ${}^{143}\text{Nd}{}^{\mathrm{l44}}\text{Nd}$ by factors of 1.5–3 in terrestrial and lunar materials. Lu-Hf studies therefore have a major contribution to make in understanding of terrestrial and other planetary evolution through time, and this is the principal importance of Lu-Hf. New data on basalts from oceanic islands show unequivocally that whereas considerable divergences occur in ${}^{176}\text{Hf}{}^{177}\text{Hf}\text{-}{}^{87}\text{Sr}{}^{86}\text{Sr}$ and ${}^{143}\text{Nd}{}^{\mathrm{l44}}\text{Nd}\text{-}{}^{87}\text{Sr}{}^{86}\text{Sr}$ diagrams, ${}^{176}\text{Hf}{}^{177}\text{Hf}$ and ${}^{143}\text{Nd}{}^{144}\text{Nd}$ display a single, linear isotopic variation in the suboceanic mantle. These discordant ${}^{87}\text{Sr}{}^{86}\text{Sr}$ relationships may allow, with the acquisition of further Hf-Nd-Sr isotopic data, a distinction between processes such as mantle metasomatism, influence of seawater-altered material in the magma source, or recycling of sediments into the mantle. In order to evaluate the Hf-Nd isotopic correlation in terms of mantle fractionation history, there is a need for measurements of Hf distribution coefficients between silicate minerals and liquids, and specifically for a knowledge of Hf behavior in relation to rareearth elements. For studying ancient terrestrial Hf isotopic variations, the best quality Hf isotope data are obtained from granitoid rocks or zircons. New data show that very U-Pb discordant zircons may have upwardly-biased ${}^{176}\text{Hf}{}^{177}\text{Hf}$, but that at least concordant to slightly discordant zircons appear to be reliable carriers of initial ${}^{176}\text{Hf}{}^{177}\text{Hf}$. Until the controls on addition of radiogenic Hf to zircon are understood, combined zircon-whole rock studies are recommended. Lu-Hf has been demonstrated as a viable tool for dating of ancient terrestrial and extraterrestrial samples, but because it offers little advantage over existing methods, is unlikely to find wide application in pure chronological studies.  相似文献   

Astronomical Engineering: A Strategy For Modifying Planetary Orbits     

D.G. Korycansky  Gregory Laughlin  Fred C. Adams 《Astrophysics and Space Science》2001,275(4):349-366

The Sun's gradual brightening will seriously compromise the Earth'sbiosphere within 10⁹ years. If Earth's orbit migrates outward,however, the biosphere could remain intact over the entiremain-sequence lifetime of the Sun. In this paper, we explore thefeasibility of engineering such a migration over a long timeperiod. The basic mechanism uses gravitational assists to (in effect)transfer orbital energy from Jupiter to the Earth, and therebyenlarges the orbital radius of Earth. This transfer is accomplishedby a suitable intermediate body, either a Kuiper Belt object or a mainbelt asteroid. The object first encounters Earth during an inward passon its initial highly elliptical orbit of large ( 300 AU)semimajor axis. The encounter transfers energy from the object to theEarth in standard gravity-assist fashion by passing close to theleading limb of the planet. The resulting outbound trajectory of theobject must cross the orbit of Jupiter; with proper timing, theoutbound object encounters Jupiter and picks up the energy it lost toEarth. With small corrections to the trajectory, or additionalplanetary encounters (e.g., with Saturn), the object can repeat thisprocess over many encounters. To maintain its present flux of solarenergy, the Earth must experience roughly one encounter every 6000years (for an object mass of 10²² g). We develop the details ofthis scheme and discuss its ramifications.  相似文献   

Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?     

Yongjun Gao  Jochen Hoefs  Eric Hellebrand  Anette von der Handt  Jonathan E. Snow 《Contributions to Mineralogy and Petrology》2007,153(4):429-442

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.  相似文献   

Paleolimnological assessment of human impacts on an urban South African lake     

F. García-Rodríguez  C. R. Anderson  J. B. Adams 《Journal of Paleolimnology》2007,38(3):297-308

North End Lake is a polluted and eutrophic freshwater system located in Port Elizabeth, South Africa. Since the lake is expected to be used for recreational/tourist purposes by 2010, a rehabilitation program will have to be designed. For this reason, we retrieved a sediment core from the central region of the lake to decipher the effect of historical human impacts on the water body. Pre-disturbance paleolimnological inferences indicate that the lake was likely mesotrophic. After ∼1831, when sheep farming activities were undertaken in the catchment, increases in trophic state and changes in sediment composition were observed. After ∼1937, increases in trace metal levels, organic matter, spheroidal carbonaceous particles (SCP) and changes in sediment composition were recorded. The system became eutrophic as indicated by the dominance of the diatom Actinocyclus normanii, a cosmopolitan species often observed in systems where water quality has been dramatically degraded. The conditions worsened after 1986 because of the construction of a storm-water retention system, which intentionally channeled storm-water runoff into the lake. Because of this, extremely high values of fecal coliforms (i.e. 2 × 10⁶ every 100 ml) have been measured in the water column. The paleolimnological information identified the sharp increase in organic content in the uppermost section of the core, and this could be correlated to the operation of the storm-water retention system. Therefore, as an immediate management measure, we suggest that the storm-water retention system should either no longer be utilized, or the storm-water runoff should be treated before disposal into the lake. In addition, an effective sewage system has to be constructed.  相似文献   

The effects of organic removal treatment on the integrity of δ<Superscript>18</Superscript>O measurements from biogenic silica     

Jonathan J. Tyler  Melanie J. Leng  Hilary J. Sloane 《Journal of Paleolimnology》2007,37(4):491-497

Prior to oxygen isotope analysis of biogenic silica by fluorination techniques, sediments must be cleaned of all organic compounds. Despite the expanding volume of research utilising oxygen isotope ratios in biogenic silica in palaeoclimatology, very little is known about the effects of different standard preparation methods for the removal of organic matter on the isotope values. Here we compare a number of methods for the removal of organic matter in order to assess their effectiveness and influence on subsequent isotope measurements. Not all the methods described here effectively removed organic matter, the best treatments were H₂O₂ and ignition in air at 550°C. Ignition in air at 950°C, and heating in vacuum at 250 and 450°C results in marked alteration of isotope values, whereas use of hydrogen peroxide (H₂O₂), nitric acid (HNO₃) and plasma ashing have little or no effect, within the bounds of analytical error. Ignition in air at 550°C was the most effective technique, and induced no alteration of δ¹⁸O_silica, but practical constraints may limit the application of this method routinely. Our findings indicate that considerable caution is required when preparing sediment for isotope analysis of biogenic silica.  相似文献   

Controls on sediment export from the Waipaoa River basin, New Zealand     

Jonathan D. Phillips  Basil Gomez† 《Basin Research》2007,19(2):241-252

A stability model of drainage basin mass balance is used to interpret historic and prehistoric patterns of sediment production, storage and output from the Waipaoa River basin, New Zealand and assess the sensitivity of basin sediment yield to land use change in the historic period. Climate and vegetation cover changed during the late Holocene, but the drainage basin mass balance system was stable before the basin was deforested by European colonists in the late 19th and early 20th centuries. In this meso‐scale dispersal system sediment sources and sinks are closely linked, and before that time there was also little variability in the rate of terrigenous mass accumulation on the adjacent continental shelf. However, despite strong first‐order geologic controls on erosion and extensive alluvial storage, sediment delivery to the continental shelf is sensitive and highly responsive to historic hillslope destabilization driven by land use change. Alluvial buffering can mask the effects of variations in sediment production within a basin on sediment yield at the outlet, but this is most likely to occur in basins where alluvial storage is large relative to yield and where the residence time of alluvial sediment is long relative to the time scale of environmental change. At present, neither situation applies to the Waipaoa River basin. Thus, the strength of the contemporary depositional signal may not only be due to the intensity of the erosion processes involved, but also to the fact that land use change in the historic period destabilized the drainage basin mass balance system.  相似文献   

A derived probability distribution approach to stormwater quality modeling     

Jieyun Chen  Barry J. Adams 《Advances in water resources》2007

The closed-form analytical stormwater quality models are developed for simulating urban catchment pollutant buildup and washoff processes. By integrating the rainfall–runoff transformation with pollutant buildup and washoff functions, stormwater quality measures, such as the cumulative distribution functions (CDFs) of pollutant loads, the expected value of pollutant event mean concentrations (EMCs) and the average annual pollutant load can be derived. This paper presents methodologies and major procedures for the development of urban stormwater quality models based on derived probability distribution theory. In order to investigate the spatial variation in model parameters and its impact on stormwater pollutant buildup and washoff processes as well as pollutant loads to receiving waters, an extended form of the original rainfall–runoff transformation which is based on lumped runoff coefficient approach is proposed to differentiate runoff generation mechanisms between the impervious and pervious areas of the catchment. In addition, as a contrast to the aggregated pollutant buildup models formulated with a single lumped buildup parameter, the disaggregated form of the pollutant buildup model is proposed by introducing a number of physically-based parameters associated with pollutant buildup and washoff processes into the pollutant load models. The results from the case study indicate that analytical urban stormwater management model are capable of providing results in good agreement with the field measurements, and can be employed as alternatives to continuous simulation models in the evaluation of long-term stormwater quality measures.  相似文献   

Flow and deposition of pyroclastic granular flows: A type example from the 1975 Ngauruhoe eruption,New Zealand     

Gert Lube  Shane J. Cronin  Thomas Platz  Armin Freundt  Jonathan N. Procter  Cargill Henderson  Michael F. Sheridan 《Journal of Volcanology and Geothermal Research》2007

Small-volume pyroclastic density currents (PDCs) are generated frequently during explosive eruptions with little warning. Assessing their hazard requires a physical understanding of their transport and sedimentation processes which is best achieved by the testing of experimental and numerical models of geophysical mass flows against natural flows and/or deposits. To this end we report on one of the most detailed sedimentological studies ever carried out on a series of pristine small-volume PDC deposits from the 1975 eruption of Ngauruhoe volcano, whose emplacement were also witnessed during eruption. Using high-resolution GPS surveys, a series of lateral excavations across the deposits, and bulk sedimentological analysis we constrained the geomorphology, internal structure and texture of the deposits with respect to laterally varying modes of deposition.  相似文献   

Fourcade: the Centenary of a Stereoscopic Method of Photographic Surveying     

Laurence P. Adams 《The Photogrammetric Record》2001,17(98):225-242

In the Preface to his book, The Four Faces of Fourcade, Clare Storrar (1990) wrote: "It is di.cult to appreciate the breadth and depth of Henry Georges Fourcade's intelligence and creative power. He was an intellectual giant, a phenomenon, whose theoretical and practical achievements have never received proper recognition. These were all the more remarkable because he began his original work on photogrammetry when science in South Africa was in its infancy, and he laboured alone far from libraries and other research facilities. His only higher academic training was in land surveying. He was adept in each of four sciences at various stages in his life, but, mainly because of his natural reserve, his reputation was highly compartmentalised. To foresters he was 'the most brilliant forestry officer of his time' to surveyors, he was exceptionally learned in theory and skilled in practice. Photogrammetry was a new subject, unheard of, except by a handful of scientists. In botany, which he took up seriously at the age of fifty-five, his work was highly regarded by leading botanists in South Africa and in Europe. All stood in awe of his extraordinary talent and ability. Some were frightened of him. But few were able—in fact, not even the best brains were wholly qualified—to grasp fully the tremendous intellectual stature and potential of this protean man."
This paper briefly describes the historic achievements of Henry Georges Fourcade, with the emphasis on his land surveying and, in particular, his photogrammetric contributions to science. The centenary of one of these, his proposal of a stereoscopic method of photographic surveying, occurs in October 2001.  相似文献   

Global-Scale Relationships between Climate and the Dengue Fever Vector, Aedes Aegypti     

Marianne J. Hopp  Jonathan A. Foley 《Climatic change》2001,48(2-3):441-463

Considerable interest exists inthe potential role climate may play in human healthissues, especially regarding the effect of climatechange on vector-borne disease. The Aedesaegypti mosquito, the principal vector for dengue,considered the most important vector-borne viraldisease in the world, is particularly susceptible toclimate variability and climatic change. Here wepresent a modeling analysis focusing on global-scaleassociations between climate and the development,potential distribution, and population dynamics ofAe. aegypti. We evaluate the model by comparingand contrasting model data with observed mosquitodensities. There is good agreement between theobserved and modeled global distribution of themosquito; however, the model results suggest thepotential for increased latitudinal distributionsduring warmer months. Seasonal fluctuations inmosquito abundance also compare well to observed data. Discrepancies possibly reflect the relatively lowresolution of the climate data and model output andthe inability of the model to account for localmicroclimate effects, especially in coastal areas.Future modeling efforts will involve study ofinterannual variability in mosquito dynamics.  相似文献